Tunable porosity of 3D-networks with germanium nodes.

نویسندگان

  • Laure Monnereau
  • Thierry Muller
  • Mathias Lang
  • Stefan Bräse
چکیده

Eight hyper cross-linked polymers based on tetrakis(4-ethynylphenyl)germanium and tetrakis(4-ethynylphenyl)methane are presented. After investigation of their N2 adsorption properties at 77 K, the porosity of the germanium-based porous organic polymers (POPs) was modulated under acidic conditions, offering an easy and direct way, in a single step, to tune the adsorption properties.

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عنوان ژورنال:
  • Chemical communications

دوره 52 3  شماره 

صفحات  -

تاریخ انتشار 2016